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Organic Chemistry

Unit 1
Carbon bonds
Introduction to Carbon BondsTypes of Carbon BondsBond Lengths and StrengthsHybridization of Carbon Atoms
Unit 3 • Chapter 2

Nomenclature of Aldehydes

Video Summary

Aldehydes, characterized by a carbonyl group (C=O) at the terminal carbon, follow specific naming conventions. In IUPAC nomenclature, the longest carbon chain containing the aldehyde group is identified as the parent chain. The suffix '-al' is added to indicate the presence of an aldehyde functional group. The parent chain is numbered, starting from the aldehyde carbon (C=O) as carbon 1. Substituents are named and numbered accordingly, using prefixes to denote their position and type. Common names, often derived from historical or naturally occurring sources, are also used for some aldehydes, such as formaldehyde (methanal) and acetaldehyde (ethanal). These common names are less systematic but widely recognized. When the aldehyde group is attached to a ring, the suffix '-carbaldehyde' is used. Understanding these rules is crucial for correctly naming and identifying aldehydes in organic chemistry.

Knowledge Check

What is the IUPAC name for CH3CH2CHO?

Which suffix is used to denote an aldehyde functional group in IUPAC nomenclature?

What is the common name for methanal?

How would you name the aldehyde with the structure: (CH3)2CHCHO?