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Organic Chemistry

Unit 1
Carbon bonds
Introduction to Carbon BondsTypes of Carbon BondsBond Lengths and StrengthsHybridization of Carbon Atoms
Unit 1 • Chapter 2

Types of Carbon Bonds

Video Summary

Carbon's ability to form diverse bonds is crucial to its role as the fundamental element of organic chemistry. The most common types are single, double, and triple bonds, distinguished by the number of electron pairs shared between carbon atoms. Single bonds (sigma bonds) involve one shared electron pair, resulting in free rotation around the bond axis and longer bond lengths. Double bonds consist of one sigma bond and one pi bond (formed by the sideways overlap of p-orbitals), leading to shorter bond lengths and restricted rotation. Triple bonds comprise one sigma bond and two pi bonds, exhibiting the shortest bond lengths and even more restricted rotation. These differences in bond order significantly impact a molecule's geometry, reactivity, and overall properties. Beyond these, carbon can also form bonds with other elements like hydrogen, oxygen, nitrogen, and halogens, influencing the molecule's characteristics. The types of bonds present dictate the molecule's three-dimensional structure and chemical behavior.

Knowledge Check

Which type of carbon bond allows for free rotation around the bond axis?

A carbon-carbon double bond consists of:

Which of the following carbon bonds is the shortest and strongest?