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Organic Chemistry

Unit 1
Carbon bonds
Introduction to Carbon BondsTypes of Carbon BondsBond Lengths and StrengthsHybridization of Carbon Atoms
Unit 1 • Chapter 1

Introduction to Carbon Bonds

Video Summary

Carbon's unique ability to form strong covalent bonds with other carbon atoms and various elements is fundamental to the diversity of organic molecules. This property, known as catenation, allows carbon to create long chains, branched structures, and rings. The four valence electrons of carbon enable it to form single, double, and triple bonds, influencing the shape and reactivity of the molecule. Single bonds (sigma bonds) are formed by the head-on overlap of atomic orbitals, resulting in free rotation around the bond axis. Double bonds (one sigma and one pi bond) and triple bonds (one sigma and two pi bonds) exhibit restricted rotation due to the side-by-side overlap of p orbitals in pi bonds. The type of carbon-carbon bond (single, double, or triple) significantly affects the molecule's properties, including its physical state, melting point, boiling point, and chemical reactivity. Understanding carbon bonding is crucial to grasping the structures and functions of all organic compounds.

Knowledge Check

What is the key property of carbon that allows it to form a vast array of molecules?

What type of bond is characterized by the head-on overlap of atomic orbitals and allows free rotation?

A carbon atom can form a maximum of how many bonds?

Which type of bond restricts rotation around the bond axis?