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Organic chemistry

Unit 1
carbon bonds
Introduction to Carbon BondsTypes of Carbon BondsDrawing Lewis Structures
Unit 1 • Chapter 2

Types of Carbon Bonds

Video Summary

Carbon's ability to form diverse bonds is crucial to its role as the backbone of organic molecules. The primary types of carbon-carbon bonds are single, double, and triple bonds. Single bonds (C-C) involve one shared electron pair, resulting in a sigma bond and free rotation around the bond axis. This leads to flexibility in the molecule's structure. Double bonds (C=C) consist of one sigma and one pi bond, restricting rotation and introducing rigidity. The pi bond forms from the sideways overlap of p-orbitals. Triple bonds (C≡C) comprise one sigma and two pi bonds, creating even greater rigidity and shorter bond length. The type of bond significantly impacts a molecule's geometry, reactivity, and physical properties. For instance, the presence of double or triple bonds can lead to isomerism (cis-trans or geometric isomers). Understanding these bond variations is essential for comprehending the vast diversity and functionality of organic compounds.

Knowledge Check

Which type of carbon-carbon bond allows for free rotation around the bond axis?

A double bond between two carbon atoms consists of:

What is a consequence of the presence of double or triple bonds in a molecule?

Which bond type is the shortest and strongest?